Chemo- and regioselective reductive transposition of allylic alcohol derivatives via iridium or rhodium catalysis.
نویسندگان
چکیده
We report highly chemo- and regioselective reductive transpositions of methyl carbonates to furnish olefin products with complementary regioselectivity to that of established Pd-catalysis. These Rh- and Ir-catalysed transformations proceed under mild conditions and enable selective deoxygenation in the presence of functional groups that are susceptible to reduction by metal hydrides.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 52 5 شماره
صفحات -
تاریخ انتشار 2016